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- 1. Nature 210, 692 (1966) , “DISTRIBUTION OF SUBSTITUTIONAL NITROGEN DONORS IN SYNTHETIC DIAMONDS”, M. J. A. Smith, B. R. Angel, R. G. EmmonsConsiderable attention has been devoted to the study of nitrogen impurity in natural diamonds using the technique of electron spin resonance1-3. The spectrum obtained in due to the unpaired electron provided by the substitutional nitrogen atom and the main feature is a triplet at g = 2.0024 caused by interaction with the nitrogen nucleus which has a spin of unity. The distribution of nitrogen is variable and would seem to depend on the method by which the diamond was formed. (Read more)
- 2. Nature 194, 829 (1962) , “DIAMONDS CONTAINING CONTROLLABLE IMPURITY CONCENTRATIONS”, C. M. Huggins, P. CannonThe presence of cosiderable quantities of impurities in natural diamond has recently been confirmed1,2. This led Frank3 to remark that multiple techniques of examination must be used on such material. In view of the report of Yoneda4 concerning possible effects of nitrogen on the X-ray diffraction patterns of diamond, it seems worth-while to us to comment further on some of the results which we have gained by the deliberate introduction of a given impurity into laboratory-grown diamond. We shall limit ourselves to a qualitative examination of the electron spin resonance spectra of a few specimens, in the belief that the profundity of the effects suffices to establish that progress in this area is now limited by the composition variability of natural diamond. (Read more)
- 3. Nature 173, 439 (1954) , “PARAMAGNETIC RESONANCE IN NEUTRON-IRRADIATED DIAMOND AND SMOKY QUARITZ”, Dr. J. H. E. Griffiths, J. Owen, I. M. WardThe nature of lattice defects in neutron-irradiated diamond is a problem of current interest. These defects are known to cause changes in some of the physical properties1 and give rise to a paramagnetic absorption spectrum. We have measured this spectrum in the temperature-range 20º-290ºK., using wave-lengths of 1-2 and 3-1 cm. There are many closely spaced lines, of which two main types can be distinguished. (Read more)
- 4. Nature 198, 981 (1963) , “Electron Spin Resonance in Neutron-irradiated Diamond”, E. A. Faulkner, E. W. J. Mitchell, P. W. WhippeyRecent work has shown that the nature of the electron spin resonance spectrum observed in irradiated diamond depends on the type and amount of irradiation. Faulkner and Lomer used comparatively heavy doses of 2-MeV electrons (up to 8×1019 electron cm-3) and distinguished four systems, all of which show a g-value which is isotropic and equal to the free-spin value within 0-2 per cent: (a) asingle line of width about 5 gauss; (b) a system of 24 lines with symmentry axes near the <221> directions, and a D-value of 0-14 cm-1; (c) a system of 6 lines with symmentry axes along the <100> directions and a D-value of 0-14 cm-1; (d) a broad absorption with a half-power width of about 70 gauss, showing a complicated anisotropic structure. (Read more)
- 5. Nature 210, 1037 (1966) , “Electron Spin Resonance Spectra associated with Nitrogen in Diamonds”, H. J. Bower, M. C. R. SymonsMANY diamonds show an electron spin resonance spectrum which has been attributed to the presence of single nitrogen atoms substituted for carbon at a diamond lattice site. Smith etal.1 found four types of nitrogen donors, equally abundant and differing only in their hyperfine axes, these being the four C–N bond directions. They measured the hyperfine coupling constants for 14N(I=1), and for 13C(I = ½) in the nearest neighbour positions (denoted centre I). Loubser and du Preez2 found additional lines in the spectrum, which they attributed to interaction of the unpaired electron with carbon-13 at other lattice sites (centres II, III and IV). The hyperfine coupling constants are recorded in Table 1, together with the orbital populations. These populations were obtained using values of |ψ2s(0)|2 and
-3>2p calculated from self-consistent-field atomic wave functions derived by Mayers and by Roothaan and Clementi (see ref. 3). (We have omitted any correction for the δ+ charge on nitrogen and the δ- charge on carbon: this would increase the spin density on carbon at the expense of the nitrogen.) (Read more) - 6. phys. stat. sol. (a) 25, 541 (1974) , “Electron Paramagnetic Resonance in Diamond Implanted at Various Energies and Temperatures”, P. R. Brosious, Y. H. Lee, J. W. Corbett, L. J. ChengAmorphous carbon layer EPR measurements have been fitted to a model which predicts the critical fluences at which the layer forms for any temperature and ion species; it predicts the layer will not form during nitrogen ion implantation in diamond above 1031°K. A new anisotropic EPR spectrum labeled D-A4 is observed after hot-implantation (650°C) with nitrogen ions. It is thought to be a spin-one-center arising from a small D-tensor interaction with <111> symmetry. Hot implantation suppresses the formation of the amorphous layer and enhances creation of crystalline lattice defects. (Read more)
- 7. Phys. Rev. Lett. 2, 39 (1959) , “ELECTRON SPIN RESONANCE OF ACCEPTOR STATES IN DIAMOND”, W. V. Smith, I. L. Gelles, and P. P. SorokinPrevious work reporting electron spin resonance in diamond has been concerned exclusively with paramagnetic centers produced by irradiation with fast neutrons. Using standard resonance techniques we have recently detected at room temperature a family of weak, narrow resonance lines near g=2... (Read more)
- 8. Phys. Rev. Lett. 10, 220 (1963) , “ELECTRON PARAMAGNETIC RESONANCE INVESTIGATION OF THE VACANCY IN DIAMOND”, John A. Baldwin, Jr.Griffiths, Owen, and Ward reported that diamonds exposed to reactor neutrons developed an intense isotropic electron paramagnetic resonance (EPR) absorption lone whose g value was very close to that of the free electron. They found that a similar line was produced by 1-MeV electrons. The work herein... (Read more)
- 9. J. Opt. Soc. Am. B 10, 913 (1993) , “Raman-heterodyne-detected nonlinear susceptibility with an arbitrary radio-frequency field strength”, X. -F. He, P. T. H. Fisk, N. B. MansonRaman-heterodyne-detected complex nonlinear susceptibility has been measured and analyzed in detail with a radio-frequency field strength varying from weak to strong. The experiments were carried out on the nitrogen-vacancy color center in diamond involving both nuclear magnetic resonance and electron paramagnetic resonance transitions. The dispersive and the absorptive components of the nonlinear susceptibility are shown to have different saturation behaviors, and an anomalous-amplitude line shape arises where the dispersion component dominates in the response spectrum at high RF powers. The experimental results are found to be in good agreement with theoretical profiles, where no adjustable parameter is included in the calculation. (Read more)
- 10. J. Opt. Soc. Am. B 9, 768 (1992) , “Origin of persistent hole burning of N-V centers in diamond”, D. Redman, S. Brown, S. C. RandNew satellite features and antiholes in the persistent hole-burning spectrum of N–V centers in diamond, as well as their dependences on applied electric fields and frequency within the inhomogeneous absorption line, are reported. These results, together with reassignments of spin states of this center, permit an understanding of the origin of the satellite holes as well as of possible mechanisms for the persistent hole-burning phenomenon itself. In addition we report narrow optical interference fringes in heterodyne-detected spectra of persistent spectral holes in the N–V defect center in diamond and discuss a recent suggestion for high-resolution Ramsey-fringe hole-burning spectroscopy of solids based on phase-separated fields. (Read more)
- 11. Opt. Lett. 15, 1094 (1990) , “Raman heterodyne detected electron-nuclear-double-resonance measurements of the nitrogen-vacancy center in diamond”, N. B. Manson, X. -F. He, P. T. H. FiskWe report two new applications of the Raman heterodyne detection technique. Raman heterodyne detected electron-nuclear double resonance and a double rf resonance technique are used to obtain the hyperfine structure of the nitrogen-vacancy center in diamond. (Read more)
- 12. Opt. Lett. 15, 983 (1990) , “Raman heterodyne detection of electron paramagnetic resonance”, K. Holliday, X. -F. He, P. T. H. Fisk, N. B. MansonWe report the detection of an electron paramagnetic resonance signal using Raman heterodyne spectroscopy, a rf –optical double-resonance technique. The signals are associated with the nitrogen-vacancy center in diamond, which has a spin-triplet ground state. A three-line spectrum associated with the nitrogen hyperfine structure is observed for various magnetic field strengths and crystal orientations. (Read more)
- 13. phys. stat. sol. (a) 21, 677 (1974) , “EPR Measurements in Ion-Implanted Diamond”, P. R. Brosious, J. W. Corbett, J. C. BourgoinA new EPR spectrum, arising from defects in diamond created by boron, carbon, and nitrogen ion-implantation, is observed. The spectrum, lattice damage production, and annealing of damage are discussed and are ascribed to amorphous carbon. (Read more)
- 14. phys. stat. sol. (a) 50, 237 (1978) , “High-Temperature Ion Implantation in Diamond”, Y. H. Lee, P. R. Brosious, J. W. CorbettC+ and N+ implantation into type IIa diamond are performed at various temperatures (25 to 1000°C) and ion-induced damage is studied by EPR measurements at 1.2 to 300 K. Hot implantation at 1000°C results in a reduced spin density of “amorphous” carbon by an order of... (Read more)
- 15. phys. stat. sol. (a) 154, 219 (1996) , “Microstructure Evolution and Defect Incorporation in Highly Oriented and Textured CVD Diamond Films”, Y. von Kaenel, J. Stiegler, E. Blank, O. Chauvet, Ch. Hellwig, K. PlamannA series of highly oriented and textured microwave CVD diamond films, where only the deposition time was varied, was deposited on silicon wafers in order to follow the evolution of the microstructure and defect content with film thickness. SEM, XRD, Raman spectroscopy, luminescence measurements, and... (Read more)
- 16. phys. stat. sol. (a) 121, 63 (1990) , “Point Paramagnetic Defects in Diamond Irradiated by High-Energy Ions”, D. P. Erchak, R. B. Grelfand, N. M. Penina, V. F. Stelmakh, V. P. Tolstykh, A. G. Ulyashin, V. S. Varichenko, A. M. ZaitsevA series of highly oriented and textured microwave CVD diamond films, where only the deposition time was varied, was deposited on silicon wafers in order to follow the evolution of the microstructure and defect content with film thickness. SEM, XRD, Raman spectroscopy, luminescence measurements, and... (Read more)
- 17. phys. stat. sol. (a) 181, 5-10 (2000) , “ESR Study of Phosphorus Implanted Type IIa Diamond”, N. Casanova, E. Gheeraert, A. Deneuville, C. Uzan-Saguy, R. KalishCold Implantation and Rapid Annealing (CIRA) at 1050 °C of P in IIa diamond crystal, then further annealing at 1400 °C were performed. EPR signals were obtained in particular (i) around g = 2.003, from “dangling bond” defects whose total concentration increases with the dose and decreases... (Read more)
- 18. phys. stat. sol. (b) 245, 1298-1314 (2008) , “EPR identification of intrinsic defects in SiC”, J. Isoya, T. Umeda, N. Mizuochi, N. T. Son, E. Janzen, T. OhshimaThe structure determination of intrinsic defects in 4H-SiC, 6H-SiC, and 3C-SiC by means of EPR is based on measuring the angular dependence of the 29Si/13C hyperfine (HF) satellite lines, from which spin densities, sp-hybrid ratio, and p-orbital direction can be determined over... (Read more)Si SiC diamond| EPR Theory electron-irradiation thermal-meas./anneal-exp.| +1 -1 0(neutral) 1.0eV~ 13C 29Si C1h C3v Carbon Csi D2d EI5/6 HEI1 HEI9/10 P6/7 Silicon T1 Td Tv2a V1/2/3 Vc Vsi antisite dangling-bond mono(=1) motional-effect n-type p-type pair(=2) quartet semi-insulating spin-relaxation triplet vacancy .inp files: SiC/Baranov/Baranov_g.inp SiC/EI5_C1h/5.inp SiC/EI5_C3v/5.inp SiC/EI6_RT/6.inp SiC/HEI10/HEI10a.inp SiC/HEI10/HEI10b.inp SiC/HEI1_C1h/1.inp SiC/HEI9/HEI9a.inp SiC/HEI9/HEI9b.inp SiC/SI5_C1h/4.inp SiC/Ky2/Ky2.inp SiC/Tv2a/Main.INP SiC/Vsi-_II_4H/Main.INP SiC/Vsi-_II_6H/Main.INP SiC/Vsi-_I_4H/Main.INP SiC/Vsi-_I_6H/Main.INP | last update: Takahide Umeda
- 19. phys. stat. sol. (b) 210, 13 (1999) , “Neutral Vacancies in Group-IV Semiconductors”, A. Zywietz, J. Furthmüller, F. BechstedtAb initio plane-wave-supercell calculations are performed for the neutral monovacancies in silicon, silicon carbide and diamond using ultrasoft non-normconserving Vanderbilt pseudopotentials. We study the structure, the energetics and the single-particle energy spectrum. The local symmetry, the... (Read more)
- 20. Phys. Rev. B 74, 245216 (2006) , “Influence of excited states of a deep substitutional dopant on majority-carrier concentration in semiconductors”, Hideharu MatsuuraThe density (NA) and energy level (EA) of an acceptor in a p-type wide-band-gap semiconductor (e.g., SiC, GaN, and diamond) are determined by a least-squares fit of the charge neutrality equation to the temperature dependence of the hole... (Read more)
- 21. Phys. Rev. B 74, 235434 (2006) , “Transport properties of n-type ultrananocrystalline diamond films”, I. S. Beloborodov, P. Zapol, D. M. Gruen, and L. A. CurtissWe investigate transport properties of ultrananocrystalline diamond films for a broad range of temperatures. Addition of nitrogen during plasma-assisted growth increases the conductivity of ultrananocrystalline diamond films by several orders of magnitude. We show that films produced at low... (Read more)
- 22. Phys. Rev. B 74, 140502(R) (2006) , “Lattice parameters and thermal expansion of superconducting boron-doped diamonds”, V. V. Brazhkin, E. A. Ekimov, A. G. Lyapin, S. V. Popova, A. V. Rakhmanina, S. M. Stishov, V. M. Lebedev, Y. Katayama, and K. KatoUsing two different high-pressure techniques, we have prepared boron-doped diamonds with atomic concentration of the dopant ranging from 0.04% to 4% (from 7×1019 to 7×1021 atom/cm3) and studied the lattice constants and thermal expansion of the diamonds... (Read more)
- 23. Phys. Rev. B 74, 161203(R) (2006) , “Room-temperature manipulation and decoherence of a single spin in diamond”, R. Hanson, O. Gywat, and D. D. AwschalomWe report on room-temperature coherent manipulation of the spin of a single nitrogen-vacancy center in diamond and a study of its coherence as a function of magnetic field. We use magnetic resonance to induce Rabi nutations and apply a Hahn spin echo to remove the effect of low-frequency dephasing.... (Read more)
- 24. Phys. Rev. Lett. 98, 216103 (2007) , “Influence of Cumulenic Chains on the Vibrational and Electronic Properties of sp-sp2 Amorphous Carbon”, L. Ravagnan, P. Piseri, M. Bruzzi, S. Miglio, G. Bongiorno, A. Baserga, C. S. Casari, A. Li Bassi, C. Lenardi, Y. Yamaguchi, T. Wakabayashi, C. E. Bottani, and P. MilaniWe report the production and characterization of a form of amorphous carbon with sp-sp2 hybridization (atomic fraction of sp hybridized species 20%) where the predominant sp bonding appears to be (=C=C=)n cumulene.... (Read more)
- 25. Phys. Rev. Lett. 98, 135506 (2007) , “Possible Approach to Overcome the Doping Asymmetry in Wideband Gap Semiconductors”, Yanfa Yan, Jingbo Li, Su-Huai Wei, and M. M. Al-JassimThe asymmetry doping problem has severely hindered the potential applications of many wideband gap (WBG) materials. Here, we propose a possible approach to overcome this long-standing doping asymmetry problem for WBG semiconductors. Our approach is based on the reduction of the ionization energies... (Read more)
- 26. Phys. Rev. B 75, 033301 (2007) , “Microscopic evidence for evolution of superconductivity by effective carrier doping in boron-doped diamond: 11B-NMR study”, H. Mukuda, T. Tsuchida, A. Harada, Y. Kitaoka, T. Takenouchi, Y. Takano, M. Nagao, I. Sakaguchi, T. Oguchi, and H. KawaradaWe have investigated the superconductivity discovered in boron-doped diamonds by means of 11B-NMR on heteroepitaxially grown (111) and (100) films. 11B-NMR spectra for all of the films are identified to arise from the substitutional B(1) site as single occupation and lower... (Read more)
- 27. Phys. Rev. B 75, 075202 (2007) , “Theoretical study of Li and Na as n-type dopants for diamond”, J. P. Goss and P. R. BriddonPhosphorus is the n-type dopant of choice for diamond, but results in a deep donor level and alternatives are being sought. One possibility is the incorporation of interstitial alkali metal impurities such as Li and Na. We present the results of density-functional calculations used to predict... (Read more)
- 28. J. Appl. Phys. 100, 124315 (2006) , “Magnetic resonance study of Ni nanoparticles in single-walled carbon nanotube bundles”, A. A. Konchits, F. V. Motsnyi, Yu. N. Petrov, S. P. Kolesnik, V. S. Yefanov, M. L. Terranova, E. Tamburri, S. Orlanducci, V. Sessa, and M. RossiWe present a detailed study of the electron magnetic resonance (EMR) properties of Ni nanoparticles (NPs) placed in the bundles of single-walled carbon nanotubes produced by arc discharge with Ni catalyst. The behavior of EMR signals has been investigated in the 10–300 K temperature range for... (Read more)
- 29. Appl. Phys. Lett. 89, 173108 (2006) , “Midgap luminescence centers in single-wall carbon nanotubes created by ultraviolet illumination”, Konstantin Iakoubovskii, Nobutsugu Minami, Yeji Kim, Kanae Miyashita, Said Kazaoui, and Balakrishnan NaliniThe authors report the effect of ultraviolet (UV) illumination on optical properties of single-wall carbon nanotubes (SWCNTs) isolated using various dispersants. It is demonstrated that even weak UV light (~1 mW/cm2) can irreversibly alter the SWCNT structure, thus resulting in the... (Read more)
- 30. Appl. Phys. Lett. 89, 243101 (2006) , “Random telegraph signals and noise behaviors in carbon nanotube transistors”, Fei Liu, Kang L. Wang, Daihua Zhang, and Chongwu ZhouA random telegraph signal appears at a smaller absolute gate bias for a larger absolute drain-source bias in a carbon nanotube transistor. Its mechanism is attributed to a defect located in the drain side of the Schottky barrier carbon nanotube transistor with Ti/Au as contact material. Furthermore,... (Read more)
- 31. Appl. Phys. Lett. 90, 013104 (2007) , “Scanning tunneling microscopy investigations of hydrogen plasma-induced electron scattering centers on single-walled carbon nanotubes”, G. Buchs, P. Ruffieux, P. Gröning, and O. GröningThe authors report on the generation of localized defects on single-walled carbon nanotubes by means of a hydrogen electron cyclotron resonance plasma. The defects have been investigated using scanning tunneling microscopy (STM) and show an apparent topographic height in the STM of 1–3 ... (Read more)
- 32. Appl. Phys. Lett. 90, 023112 (2007) , “Electrically tunable defects in metallic single-walled carbon nanotubes”, Ji-Yong ParkA defect whose electron transmission probability can be controlled by electric field is intentionally created on a metallic single-walled carbon nanotube (SWCNT) with a voltage pulse from a tip of an atomic force microscope (AFM). Localized characteristics of the created defect are elucidated with... (Read more)
- 33. Phys. Rev. B 74, 245217 (2006) , “Donor levels for selected n-type dopants in diamond: A computational study of the effect of supercell size”, J. P. Goss, P. R. Briddon, and R. J. EyreComputational techniques are key predictive tools in the drive to engineer semiconductive materials. Diamond, intrinsically a wide band-gap insulator, can be made to semiconduct n-type by doping with phosphorus. However, the relatively deep level at Ec−0.6 eV... (Read more)
- 34. Appl. Phys. Lett. 89, 232111 (2006) , “Electron-beam-induced dissociation of B–D complexes in diamond”, J. Barjon, J. Chevallier, F. Jomard, C. Baron, and A. DeneuvilleThe diffusion of deuterium in boron-doped homoepitaxial diamond films leads to the passivation of boron acceptors via the formation of B–D complexes. In this letter, the stability of B–D pairs is investigated under the stress of a low-energy (10 keV) electron-beam irradiation at low... (Read more)
- 35. phys. stat. sol. (b) 215, 109 (1999) , “Zeeman Effect of Lyman Transitions: Electronic Raman Spectrum of Boron Acceptors in Diamond”, H. Kim, R. Vogelgesang, A. K. Ramdas, S. Rodriguez, M. Grimsditch, T. R. AnthonySubstitutional boron impurities in diamond exhibit characteristic Lyman transitions, originating in the lower 1s(p3/2): 8 ground state and terminating in its spin-orbit split 1s(p1/2): 7 counterpart. In addition to the Lyman spectrum observed in the... (Read more)
- 36. phys. stat. sol. (a) 172, 113 (1999) , “On Photocurrent (and EPR) Study of Defect Levels in CVD Diamond”, J. Rosa, M. Van??ek, M. Nesldek, L. M. StalsPhotocurrent spectroscopy is used for studying electronic defect states in the gap of optical-quality CVD diamond. The constant photocurrent method (CPM), allowing to measure the optical (photoionization) cross-section of defects, is applied on samples with a different surface treatment. The... (Read more)
- 37. phys. stat. sol. (a) 174, 137 (1999) , “Effect of Stress on Optical and ESR Lines in CVD Diamond”, K. Iakoubuvskii, A. Stesmans, G. J. Adriaenssens, R. Provoost, R. E. Silverans, V. RaikoCorrelation between the shape of Raman, photoluminescence (PL) and Electron Spin Resonance (ESR) signals in CVD diamond films was examined for both undoped and nitrogen-doped films. No correlation was observed between the shift of the diamond Raman line and its linewidth, even for the films produced... (Read more)
- 38. Phys. Rev. B 59, 12900 (1999) , “Electron-paramagnetic-resonance measurements on the divacancy defect center R4/W6 in diamond”, D. J. Twitchen, M. E. Newton, J. M. Baker, T. R. Anthony, W. F. BanholzerElectron-paramagnetic-resonance (EPR) studies in radiation damaged diamond enriched to 5% 13C have resulted in the identification of the nearest-neighbor divacancy center. It is the isotopic enrichment, and consequent observation of 13C hyperfine lines, that has permitted the... (Read more)
- 39. phys. stat. sol. (a) 186, 167-176 (2001) , “What We Have Learned about Intrinsic Defects in Silicon: A Help in Understanding Diamond?”, G. D. WatkinsWhat we have established by electron paramagnetic resonance (EPR) studies in silicon concerning the properties of its intrinsic defects (vacancies and interstitials) and their interactions with other defects is reviewed. The lessons learned are compared to what is currently being observed in... (Read more)
- 40. phys. stat. sol. (a) 186, 199-206 (2001) , “Characterization of Defects in as-Grown CVD Diamond Films and HPHT Diamond Powders by Electron Paramagnetic Resonance”, K. Iakoubovskii, A. StesmansSeveral defect centers, labeled as KUL1-7, have been detected by electron paramagnetic resonance in CVD diamond films and synthetic diamond powders. Their g values were determined relatively to the P1 (NS0) center, for which the value of g = 2.00216(1) with... (Read more)
- 41. phys. stat. sol. (a) 186, 215-220 (2001) , “First Principles Study of the Self-Interstitial Defect in Diamond”, J. P. Goss, R. Jones, T. D. Shaw, M. J. Rayson, P. R. BriddonFirst principles techniques have been employed to examine the isolated self-interstitial in diamond. The assignment of the R2 EPR center to the self-interstitial has been questioned because of the small fine structure term. We have calculated the spin-spin interaction tensor, which resolves the... (Read more)
- 42. phys. stat. sol. (a) 181, 83-90 (2000) , “Relative Abundance of Single and Vacancy-Bonded Substitutional Nitrogen in CVD Diamond”, I. I. Vlasov, V. G. Ralchenko, A. V. Khomich, S. V. Nistor, D. Shoemaker, R. A. KhmelnitskiiRelations between the concentrations of neutral (N0) and charged (N+) single-substitutional nitrogen and of nitrogen-vacancy (N-V) complexes in chemical vapour deposited diamond films of 0.2 mm thickness with nitrogen impurity concentration levels of 10 ppm are studied. For... (Read more)
- 43. phys. stat. sol. (b) 217, 665-684 (2000) , “Paramagnetic Defects”, U. Gerstmann, M. Amkreutz, H. OverhofAb-initio calculations of paramagnetic hyperfine interactions for deep defects in semiconductors provide information about the magnetization density distribution in space. A comparison of theoretical results with corresponding data from magnetic resonance experiments allows to estimate the accuracy... (Read more)
- 44. Phys. Rev. B 66, 161202(R) (2002) , “Phosphorus and sulphur doping of diamond”, L. G. Wang and Alex ZungerPrevious calculations on n-type doping of diamond by P and S predicted that S has a shallower level and a higher solubility than P. Our first-principles calculations show that the opposite is true: Phosphorus impurity in diamond gives rise to a shallower donor level, and has a higher bulk solid... (Read more)
- 45. Phys. Rev. Lett. 92, 135502 (2004) , “Hydrogen Incorporation in Diamond: The Vacancy-Hydrogen Complex”, C. Glover, M. E. Newton, P. M. Martineau, S. Quinn, D. J. TwitchenWe report the identification of the vacancy-hydrogen complex in single crystal diamond synthesized by chemical vapor deposition. The S = 1 defect is observed by electron paramagnetic resonance in the negative charge state. The hydrogen atom is bonded to one of the carbon atoms neighboring the... (Read more)
- 46. Phys. Rev. Lett. 90, 185507 (2003) , “Hydrogen Incorporation in Diamond: The Nitrogen-Vacancy-Hydrogen Complex”, C. Glover, M. E. Newton, P. Martineau, D. J. Twitchen, J. M. BakerWe report the identification of the nitrogen-vacancy-hydrogen complex in a freestanding nitrogen-doped isotopically engineered single crystal diamond synthesized by chemical vapor deposition. The hydrogen atom is located in the vacancy of a nearest-neighbor nitrogen-vacancy defect and appears to be... (Read more)
- 47. Physica B 376-377, 358-361 (2006) , “Pulsed EPR studies of Phosphorus shallow donors in diamond and SiC”, J. Isoya, M. Katagiri, T. Umeda, S. Koizumi, H. Kanda, N. T. Son, A. Henry, A. Gali, E. JanznPhosphorus shallow donors having the symmetry lower than Td are studied by pulsed EPR. In diamond:P and 3C–SiC:P, the symmetry is lowered to D2d and the density of the donor wave function on the phosphorus atom exhibits a predominant p-character. In 4H–SiC:P with the site symmetry of... (Read more)
- 48. J. Appl. Phys. 99, 104906 (2006) , “An x-ray topographic study of diamond anvils: Correlation between defects and helium diffusion”, Agnès Dewaele, Paul Loubeyre, and Ramesh AndréX-ray topographic images of several dozens of diamonds have been recorded before and after their use as anvils in a diamond anvil high pressure cell. The aim of this study is to better understand and prevent the breakage of diamond anvils when they are used in contact with a helium sample. Indeed,... (Read more)
- 49. Appl. Phys. Lett. 89, 131918 (2006) , “Hydrogen incorporation processes in nanodiamond films studied by isotopic induced modifications of Raman spectra”, Sh. Michaelson, O. Ternyak, A. Hoffman, and Y. LifshitzThe effect of replacing H by D and C-12 by C-13 in the gas species used to grow different types of nanodiamond films on the Raman spectra of these films was studied. The modifications of the Raman spectra were investigated in submicron sized diamond films grown by hot filament chemical vapor... (Read more)
- 50. Phys. Rev. Lett. 97, 137206 (2006) , “Electron Spin Resonance of Proton-Irradiated Graphite”, Kyu Won Lee and Cheol Eui LeeIn the case of colossal magnetoresistance in the perovskite manganites, "double exchange" mediated by the itinerant spins is believed to play a key role in the ferromagnetism. In contrast, the conventional "Heisenberg" interaction, i.e., direct (unmediated) interaction between... (Read more)
- 51. Phys. Rev. B 74, 104303 (2006) , “Nitrogen-vacancy center in diamond: Model of the electronic structure and associated dynamics”, N. B. Manson, J. P. Harrison, and M. J. SellarsSymmetry considerations are used in presenting a model of the electronic structure and the associated dynamics of the nitrogen-vacancy center in diamond. The model accounts for the occurrence of optically induced spin polarization, for the change of emission level with spin polarization and for new... (Read more)
- 52. Appl. Phys. Lett. 89, 122111 (2006) , “Hall electron mobility in diamond”, J. Pernot, C. Tavares, E. Gheeraert, E. Bustarret, M. Katagiri, and S. KoizumiThe low field Hall mobility of electron in diamond was investigated from room temperature to 873 K, both experimentally and theoretically. The acoustic deformation potential for electron scattering is determined by fitting of theoretical calculations to experimental data for high quality {111}... (Read more)
- 53. Phys. Rev. Lett. 97, 087601 (2006) , “Polarization and Readout of Coupled Single Spins in Diamond”, R. Hanson, F. M. Mendoza, R. J. Epstein, and D. D. AwschalomWe study the coupling of a single nitrogen-vacancy center in diamond to a nearby single nitrogen defect at room temperature. The magnetic dipolar coupling leads to a splitting in the electron spin resonance frequency of the nitrogen-vacancy center, allowing readout of the state of a single nitrogen... (Read more)
- 54. Phys. Rev. B 73, 245211 (2006) , “Hydrogen and muonium in diamond: A path-integral molecular dynamics simulation”, Carlos P. Herrero, Rafael Ramírez, and Eduardo R. HernándezIsolated hydrogen, deuterium, and muonium in diamond have been studied by path-integral molecular dynamics simulations in the canonical ensemble. Finite-temperature properties of these point defects were analyzed in the range from 100 to 800 K. Interatomic interactions were modeled by a... (Read more)
- 55. Phys. Rev. B 73, 245207 (2006) , “Photoionization measurement of deep defects in single-crystalline CVD diamond using the transient-current technique”, J. Isberg, A. Tajani, and D. J. TwitchenWe have adopted the transient-current technique as a sensitive method to detect small concentrations of charged defects in diamond and to study its photoionization spectrum. It is found that ionized impurity concentrations in the interval 1091013 cm3 can... (Read more)
- 56. Appl. Phys. Lett. 87, 222101 (2005) , “Trapping-detrapping defects in single crystal diamond films grown by chemical vapor deposition”, A. Balducci, Marco Marinelli, E. Milani, M. E. Morgada, G. Prestopino, M. Scoccia, A. Tucciarone, and G. Verona-RinatiHigh-quality single-crystal diamond films were homoepitaxially grown by chemical vapor deposition onto low cost high-pressure high-temperature diamond substrates. The transport properties of the obtained samples were studied by photoresponse characterization. Fast ultraviolet (5 ns) laser pulses at... (Read more)
- 57. Appl. Phys. Lett. 88, 091912 (2006) , “Hydrogen-vacancy related defect in chemical vapor deposition homoepitaxial diamond films studied by electron paramagnetic resonance and cathodoluminescence”, N. Mizuochi, H. Watanabe, H. Okushi, S. Yamasaki, J. Niitsuma, T. SekiguchiHydrogen-vacancy related defect (H1) in chemical vapor deposition homoepitaxial diamond films has been investigated by electron paramagnetic resonance and cathodoluminescence. It is found that the concentration of H1 significantly decreases as the dilution... (Read more)
- 58. Phys. Rev. B 73, 115204 (2006) , “Platelets and the 110a0/4 {001} stacking fault in diamond”, J. P. Goss, P. R. Briddon, R. Jones, M. I. HeggieElectron microscopy reveals the presence of {001} platelets in annealed, nitrogen containing diamond. These extended planar defects give rise to a large displacement of the surrounding material, are correlated with luminescence and optical absorption, and are characterized by the B... (Read more)
- 59. Physica B 308-310, 593 (2001) , “Electrically detected magnetic resonance studies of phosphorus doped diamond ”, T. Graf, M. S. Brandt, C. E. Nebel, M. Stutzmann and S. KoizumiPhosphorus doped n-type epitaxial diamond films have been studied by electron spin resonance (ESR) and electrically detected magnetic resonance (EDMR). At low electric field, the dominant defects influencing the electronic transport are carbon dangling bonds, while at higher fields the anisotropic... (Read more)
- 60. Solid State Commun. 9, 313 (1971) , “ELECTRON SPIN RESONANCE OF SPIN S = 1 STATES IN UNIRRADIATED DIAMONDS”, Thomas SzendreiThree types of paramagnetic centres with effective spin S = 1 have been detected in natural unirradiated type Ib diamonds. The values of the zero field spitting are 200 oe, 220 oe and 246 oe. (Read more)
- 61. J. Phys.: Condens. Matter 10, 9833 (1998) , “Optically detected electron paramagnetic resonance of Ni-related defects in synthetic diamond crystals”, Th. Pawlik, C. Noble, J. -M. SpaethSynthetic diamond crystals grown using a solvent catalyst that contains Ni were studied by optical detection of electron paramagnetic resonance (ODEPR) using the magnetic circular dichroism of the optical absorption (MCDA). The MCDA spectra in the infrared spectral region consist of a... (Read more)
- 62. Phys. Rev. 115, 1546 (1959) , “Electron-Spin Resonance of Nitrogen Donors in Diamond”, W. V. Smith, P. P. Sorokin, I. L. Gelles, and G. J. LasherElectron-spin resonance of bound substitutional nitrogen donors in diamond is observed and discussed. The g factor is isotropic at 2.00240.0005. For a given donor, one of the C-N bond directions is a hyperfine axis with constants A=40.8 oersteds, B=29.2 oersteds. There are thus four types of... (Read more)
- 63. Phys. Rev. B 42, 9843 (1990) , “EPR studies of interstitial Ni centers in synthetic diamond crystals”, J. Isoya, H. Kanda, Y. UchidaTwo new electron-paramagnetic-resonance (EPR) spectra, tentatively labeled NIRIM-1 and NIRIM-2, have been studied using synthetic diamond crystals grown from the Ni solvent to which various amounts of nitrogen getters (Ti, Zr) and/or boron were added. The NIRIM-1 spectrum (g=2.0112) having the... (Read more)diamond| EPR| NIRIM1 NIRIM2 .inp files: diamond/NIRIM1 diamond/NIRIM2 | last update: Masatoshi Sasaki
- 64. J. Phys.: Condens. Matter 10, 11781 (1998) , “Electron paramagnetic resonance investigations of nickel defects in natural diamonds”, C. J. Noble, Th. Pawlik, J. -M. SpaethElectron paramagnetic resonance (EPR) and electron nuclear double resonance (ENDOR) spectra of natural blue diamonds from the Argyle mine in Western Australia are reported for the first time. These diamonds are shown to contain the NE2 centre which has been observed primarily in synthetic diamonds... (Read more)
- 65. J. Appl. Phys. 38, 337 (1967) , “Electron Spin Resonance in Semiconducting Diamonds”, M. D. BellElectron spin resonance (ESR) was studied in five semiconducting diamonds in the temperature range 108°370°K and at 4.2°K. The g factor is 2.0030±0.0003, and the linewidth varies from 0.3 to 8 Oe at room temperature. The number of spins contributing to the ESR... (Read more)
- 66. Phys. Rev. B 54, 7881 (1996) , “Hydrogen-related defects in polycrystalline CVD diamond”, X. Zhou, G. D. Watkins, K. M. McNamara Rutledge, R. P. Messmer, S. ChawlaBy simulating the line shapes of a commonly observed S=1/2 electron paramagnetic resonance (EPR) center in polycrystalline chemical vapor deposited (CVD) diamond at 9.8, 14, 20, and 35 GHz, we conclude that the EPR signal, which we label H1, results from a unique defect with a single hydrogen atom... (Read more)
- 67. Physica B 273-274, 651 (1999) , “New paramagnetic defects in synthetic diamonds grown using nickel catalyst”, A. J. Neves, R. Pereira, N. A. Sobolev, M. H. Nazaré, W. Gehlhoff, A. Näser and H. KandaWe report four new EPR spectra found in high-pressure synthetic diamonds with high nitrogen content, grown using nickel, and annealed at 1600°C. Analyzing the complex spectra around g≈2 two trigonal and two orthorhombic defects, all with , were identified from the angular dependence and... (Read more)diamond| EPR| AB1 AB2 AB3 AB4 .inp files: diamond/AB1 diamond/AB2 diamond/AB3 diamond/AB4 | last update: Masatoshi Sasaki
- 68. Diamond Relat. Mater. 10, 480-484 (2001) , “EPR study of preferential orientation of crystallites in N-doped high quality CVD diamond”, S. Nokhrin, J. Rosa, M. Vanecek, A. G. Badalyan and M. NesladekThe directions of preferential growth of free-standing optical-quality CVD diamond wafers have been investigated with the help of electron paramagnetic resonance (EPR). EPR signals of the well-known P1 centre (substitutional nitrogen) have been used as a probe. A computer simulation of EPR spectra... (Read more)
- 69. Diamond Relat. Mater. 10, 1681-1683 (2001) , “EPR and optical imaging of the growth-sector dependence of radiation-damage defect production in synthetic diamond”, G. A. Watt, M. E. Newton and J. M. BakerEPR imaging data are presented for the distribution of single substitutional nitrogen (P1) in a synthetic diamond of mixed IIa/Ib character, and compared with the distribution of the di-001-split interstitial (R1) produced during an electron irradiation. Since the defects are localised in different... (Read more)
- 70. Diamond Relat. Mater. 10, 580-584 (2001) , “Phosphorus site after CIRA implantation of type IIa diamond”, N. Casanova, E. Gheeraert, A. Deneuville, C. Uzan-Saguy and R. KalishA set of type IIa diamond crystals was processed by cold implantation and rapid annealing at 1050°C ex situ annealing at 1400°C and investigated by ESR measurement. The ESR spectra of CIRA and post-annealed samples show an isotropic line at g=2.003, a set of anisotropic hyperfine lines,... (Read more)
- 71. Diamond Relat. Mater. 10, 434-438 (2001) , “Interstitial aggregates in diamond”, J. P. Goss, B. J. Coomer, R. Jones, T. D. Shaw, P. R. Briddon and S. ÖbergTheoretical modelling of magnetic resonance signals lead to convincing models for the first three self-interstitial aggregates in diamond. These in turn suggest the manner in which larger more stable aggregates including the platelet, observed in annealed type I diamonds, are formed. (Read more)
- 72. Sov. Phys. Solid State 10, 1789 (1969) , “THE STATE OF NITROGEN IMPURITIES IN SYNTHETIC DIAMONDS”, E. V. Sobolev, Yu. A. Litvin, N. D. Samsonenko, V. E. Ilin, S. V. Lenskaya, V. P. Butuzov
- 73. Sov. Phys. Solid State 11, 1104 (1969) , “ELECTRON PARAMAGNETIC RESONANCE OF IONIZED NITROGEN PAIRS IN DIAMOND”, M. Ya. Shcherbakova, E. V. Sobolev, N. D. Samsonenko, V. K. Aksenov
- 74. Sov. Phys. Solid State 6, 2460 (1965) , “DISTRIBUTION OF PARAMAGNETIC NITROGEN CENTERS IN SOME TYPE-I DIAMONDS”, N. D. Samsonenko
- 75. Sov. Phys. Solid State 8, 1842 (1967) , “REORIENTATION OF THE JAHN-TELLER DISTORTION IN NITROGEN IMPURITY CENTERS IN DIAMOND”, L. A. Shulman, I. M. Zaritskii, G. A. Podzyarei
- 76. Sov. Phys. Solid State 9, 1545 (1968) , “EXCHANGE PAIRS OF NITROGEN IMPURITIES IN DIAMOND”, L. A. Shulman, I. M. Zaritskii, K. A. Tikhonenko
- 77. Sov. Phys. Solid State 12, 2303 (1971) , “EFFECT OF THE SPIN-SPIN RESERVOIR ON SATURATION OF THE NITROGEN EPR LINE IN DIAMOND”, L. A. Shulman, A. B. Brik, T. A. Nachalnaya, G. A. Podzyarei
- 78. Sov. Phys. Solid State 13, 281 (1971) , “ELECTRON PARAMAGNETIC RESONANCE OF NITROGEN-ALUMINUM PAIRS IN DIAMOND”, M. Ya. Shcherbakova, E. V. Soboleva, N. D. Samsonenko, V. A. Nadolinnyi, P. V. Schastnev, A. G. Semenov
- 79. Sov. Phys. Solid State 13, 1809 (1972) , “DEFECTS IN SYNTHETIC DIAMOND POWDERS AND THE DYNAMIC JAHN-TELLER EFFECT”, Yu. A. Bratashevskii, F. N. Bukhanko, N. D. Samsonenko, O. Z. Shapiro
- 80. Sov. Phys. Solid State 14, 1521 (1972) , “EXCHANGE BROADENING OF THE HYPERFINE COMPONENTS OF THE ESR SPECTRUM OF NITROGEN IN DIAMOND”, L. A. Shulman, G. A. Podzyarei
- 81. Sov. Phys. Solid State 16, 1377 (1975) , “Cross relaxation in ESR spectra of synthetic diamonds”, L. A. Shulman, G. A. Podzyarei
- 82. Sov. Phys. Solid State 16, 2118 (1975) , “Electron paramagnetic resonance spectrum and the infrared absorption of diamonds doped with nitrogen isotopes”, Yu. A. Klyuev, V. I. Nepsha, A. M. Naletov
- 83. Sov. Phys. Solid State 17, 991 (1975) , “Electron spin resonance of Co2+ ions in synthetic diamonds”, V. S. Bagdasaryan, . A. Markosyan, M. A. Matosyan, O. S. Torosyan, E. G. Sharoyan
- 84. Sov. Phys. Solid State 18, 1883 (1976) , “Spin-lattice relaxation of a Jahn-Teller nitrogen center in diamond”, I. M. Zaritskii, V. Ya. Bratus, V. S. Vikhnin, A. S. Vishnevskii, A. A. Konchits, V. M. Ustintsev
- 85. Sov. Phys. Solid State 20, 178 (1978) , “Influence of temperature on spin-spin interaction of nitrogen and nickel centers in diamond”, V. K. Bezobchuk, A. B. Brik, I. V. Matyash, Yu. V. Fedotov
- 86. Nucl. Instrum. Methods Phys. Res. B 127-128, 217 (1997) , “Defects in ion implanted diamond films (ESR study)”, Yoshiyuki Show, Tomio Izumi, Masahiro Deguchi, Makoto Kitabatake, Takashi Hirao, Yusuke Morid, Akimitsu Hatta, Toshimichi Ito and Akio HirakiThe defect structures in ion implanted diamond films have been studied by the electron spin resonance (ESR) method. Two kinds of paramagnetic defect centers were observed in ion implanted layers. One was a carbon dangling bond that existed in crystalline diamond (g = 2.003, ΔHpp = 3 Oe), and... (Read more)
- 87. Diamond Relat. Mater. 9, 424-427 (2000) , “Experimental and theoretical studies of cobalt defects in diamond”, Karl Johnston, Alison Mainwood, Alan T. Collins, Gordon Davies, Daniel Twitchen, Mark Newton and J. M. BakerDiamonds grown with a cobalt/iron solvent catalyst and annealed at 1800°C were cut and polished along the main symmetry directions. The photoluminescence spectrum showed at least four zero phonon lines. One line at 2.367 eV splits and shifts under uniaxial stress indicating that it originates... (Read more)
- 88. Diamond Relat. Mater. 9, 417-423 (2000) , “Spectroscopy of defects and transition metals in diamond”, A. T. CollinsThis article reviews the optical and electron paramagnetic resonance (EPR) studies that have been carried out on diamonds containing nickel-related or cobalt-related defect centres. It is shown that this work is now at a stage where a real understanding may be reached about the nature of the defects... (Read more)
- 89. Diamond Relat. Mater. 9, 337-340 (2000) , “Structural changes in CVD diamond film by boron and nitrogen doping”, Yoshiyuki Show, Toshikazu Matsukawa, Hirokazu Ito, Mitsuo Iwase and Tomio IzumiThe effect of impurity atoms in the defect structures of a diamond film has been studied by electron spin resonance (ESR). It has been observed that introducing boron atoms into the diamond film during chemical vapor deposition (CVD) reduces paramagnetic defects (Pdia and Pac centers) by decreasing... (Read more)
- 90. Diamond Relat. Mater. 9, 1057-1060 (2000) , “New paramagnetic centers in annealed high-pressure synthetic diamond”, A. J. Neves, R. Pereira, N. A. Sobolev, M. H. Nazaré, W. Gehlhoff, A. Näser and H. KandaWe report three new paramagnetic centers found in high-pressure synthetic diamond with high nitrogen and nickel content and annealed at 1600°C. Analysis of the spectra has shown that two of the centers, labeled AB1 and AB2, are related to systems with effective spin S=1/2 and the other is... (Read more)
- 91. Diamond Relat. Mater. 9, 883-886 (2000) , “Mechanisms of nitrogen aggregation in nickel- and cobalt-containing synthetic diamonds”, V. A. Nadolinny, A. P. Yelisseyev, J. M. Baker, D. J. Twitchen, M. E. Newton, B. N. Feigelson and O. P. YuryevaWe present a study of the point defects observed in as-grown and annealed synthetic diamonds using electron paramagnetic resonance (EPR) and infrared spectroscopy. The diamonds were grown by the temperature gradient HPHT method in a split sphere apparatus using Fe–Ni–C or... (Read more)
- 92. Phys. Rev. B 61, 3863-3876 (2000) , “Identification of the neutral carbon ?100?-split interstitial in diamond”, D. C. Hunt, D. J. Twitchen, M. E. Newton, J. M. Baker, T. R. Anthony, W. F. Banholzer, S. S. VagaraliA systematic study has been made of some of the properties of R2, the most dominant paramagnetic defect produced in type-IIa diamond by electron irradiation. R2 has been produced in high-purity synthetic diamonds, which have been irradiated with 2 MeV electrons in a specially developed dewar,... (Read more)
- 93. Phys. Rev. B 62, 6587-6597 (2000) , “EPR data on the self-interstitial complex O3 in diamond”, D. C. Hunt, D. J. Twitchen, M. E. Newton, J. M. Baker, J. K. Kirui, J. A. van Wyk, T. R. Anthony, W. F. BanholzerA previously unreported defect, which is labeled O3, has been observed in the EPR spectrum of synthetic type-IIa diamonds irradiated at 100 K with 2 MeV electrons. This defect was not observed in identical diamonds whose temperature during electron irradiation was ?300 K. This center has also been... (Read more)
- 94. Phys. Rev. B 62, 16587-16594 (2000) , “ESR and optical evidence for a Ni vacancy center in CVD diamond”, K. Iakoubovskii, A. Stesmans, B. Nouwen, and G. J. AdriaenssensCharacterization of a series of correlated electron-spin resonance (ESR) and photoluminescence (PL) lines in diamond grown by chemical vapor deposition is reported. The series consists of a set of structured PL bands in the range 1.82.3 eV, and ESR lines due to an S=1 center with g=2.0039(1) and... (Read more)
- 95. Phys. Rev. B 62, 8038-8052 (2000) , “Zeeman effect of electronic Raman lines of acceptors in elemental semiconductors: Boron in blue diamond”, H. Kim, Z. Barticevic, A. K. Ramdas, S. Rodriguez, M. Grimsditch, T. R. AnthonyThe Zeeman effect of the electronic Raman transition from 1s(p3/2):?8 to the 1s(p1/2):?7 spin-orbit partner (??) of boron acceptors in diamond is studied with magnetic field B along [001], [111], or [110]. As many as eight Zeeman components of... (Read more)
- 96. J. Chem. Phys. 113, 744-750 (2000) , “Dynamic nuclear polarization of diamond. III. Paramagnetic electron relaxation times from enhanced 13C nuclear magnetic resonance signals”, Eduard C. Reynhardt and Grant L. HighIt is shown that by varying pulse lengths and delay times in electron spin resonance microwave pulse sequences, designed to enhance 13C nuclear magnetic resonance signals in diamond, and measuring the resulting 13C nuclear magnetic resonance signal, the paramagnetic impurity... (Read more)
- 97. J. Phys.: Condens. Matter 12, 7807-7817 (2000) , “Electron spin resonance characterization of a divacancy-related centre in CVD diamond”, A. Stesmans, B. Nouwen, K. IakoubovskiiThe electron spin resonance characterization of an undocumented paramagnetic centre in chemical vapour deposited diamond is reported. Successful fitting of the powder pattern-like spectrum characterized the originating defect as an S = 1 centre of spectroscopic splitting factor g =... (Read more)
- 98. Phys. Rev. B 61, 9-11 (2000) , “Identification of cobalt on a lattice site in diamond”, D. J. Twitchen, J. M. Baker, and M. E. NewtonWe report the finding of an electron-paramagnetic-resonance (EPR) center, labeled O4, which contains cobalt on a site in the diamond lattice. O4 is observed at low temperatures (<30?K) in high temperature and pressure synthetic diamonds grown with a cobalt containing metal-solvent catalyst after... (Read more)
- 99. Chem. Phys. Lett. 322, 273-279 (2000) , “Room-temperature field dependence of the electron spin–lattice relaxation times of paramagnetic P1 and P2 centers in diamond”, Cornelis J. Terblanche and Eduard C. ReynhardtElectron spin–lattice relaxation (SLR) times of P1 and P2 centers have been measured at 300 K at X-band and W-band for one synthetic (type-Ib) and three natural (type-Ia) diamonds using electron paramagnetic resonance spectroscopy. Bi-exponential SLR, with a fast and a slow component, was... (Read more)
- 100. J. Phys.: Condens. Matter 13, 2053-2060 (2001) , “Possible evidence of a copper-related electron paramagnetic resonance centre in diamond”, J. M. BakerThe EPR centre W36, found in natural type IIb diamond, has been previously attributed to a boron-related point defect, largely on account of its four line hyperfine structure attributed to 11B. The attribution has been re-examined, and no simple boron-related site has been found... (Read more)
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